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Oxidation of alcohols using acidified sodium or potassium dichromate(VI) solution. ... You need to produce enough of the aldehyde (from oxidation of a primary alcohol) or ketone (from a secondary alcohol) to be able to test them. There are various things which aldehydes do which ketones don't.
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www.chemguide.co.uk/organicprops/alcohols/oxidation.htm...
www.chemguide.co.uk/organicprops/alcohols/oxidation.html
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Aldehyde - Wikipedia, the free encyclopedia
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An aldehyde is an organic compound containing a terminal carbonyl group. This functional group, which consists of a carbon atom bonded to a hydrogen atom and double-bonded to an oxygen atom (chemica...
en.wikipedia.org/wiki/Aldehyde
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The reactive species in the oxidation is the hydrate formed when the aldehyde reacts with the water. ... Part 3:; A base (here a water molecule) abstracts a proton from the chromate ester, the C=O forms and a Cr species leaves. This is really an E2 elimination reaction. Note the importance of the original aldehyde H...
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www.mhhe.com/physsci/chemistry/carey/student/olc/ch17ox...
www.mhhe.com/physsci/chemistry/carey/student/olc/ch17oxidationreactions.html
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A rapid oxidation of primary and secondary alcohols using catalytic amounts of TEMPO and Yb(OTf)3 in combination with a stoichiometric amount of iodosylbenzene afforded carbonyl compounds in excellent yields without over-oxidation.
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www.organic-chemistry.org/synthesis/C2O/aldehydes/oxida...
www.organic-chemistry.org/synthesis/C2O/aldehydes/oxidationsalcohols.shtm
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Drosophila alcohol dehydrogenase (Adh) catalyses the oxidation of both alcohols and aldehydes. ... Thus the substrate specificity of the aldehyde oxidation reaction can be determined by simply measuring the NADH release. The coefficients for oxidation and dehydrogenation reactions (phi0d and phiAd respectively) are complex...
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www.medscape.com/medline/abstract/9445383
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BioInfoBank Library :: Lipid aldehyde oxidation as a physiological role for class 3 aldehyde dehydrogenases. Aldehyde dehydrogenase class 3 expression: identification of a cornea-preferred gene promoter in transgenic mice. ... The results suggest that (1) microsomal ALDH is a member of the Class 3 aldehyde dehydrogenase family,
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lib.bioinfo.pl/pmid:2043148
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Under hydrogen autotransfer conditions employing a catalyst derived from [Ir(cod)Cl]2 and BIPHEP, 1,3-cyclohexadiene (CHD) couples to benzylic alcohols 1a9a to furnish carbonyl addition products 1c9c, which appear as single diastereomers with variable quantities of regioisomeric adducts 1d9d. Under related transfer ...
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pubs.acs.org/doi/abs/10.1021/ol800159w
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Additionally, rapid alcohol−aldehyde redox equilibration in advance of carbonyl addition is demonstrated. Thus, anti-diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level is achieved in the absence of any stoichiometric metallic reagents or stoichiometric metallic byproducts...
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pubs.acs.org/doi/abs/10.1021/ja808857w
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Betaine Aldehyde Oxidation by Spinach Chloroplasts 1 ... The mechanism of betaine aldehyde oxidation was investigated with subcellular fractions from spinach leaf protoplasts. ... Stimulation of betaine aldehyde oxidation in illuminated spinach chloroplasts was due to a thylakoid activity which was sensitive to catalase;
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www.plantphysiol.org/cgi/content/abstract/82/3/753
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