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Furfural is metabolized by S. cerevisae under aerobic, oxygen-limited, and anareobic conditions to furfural alcohol. –Furfural reduce the specific growth rate, the cell-mass yield on ATP, the volumetric, and specific ethanol production; ... Mechanism of acidic acid inhibition...
biofueloutlook.blogspot.com/2009/02/mechanism-of-furfur... biofueloutlook.blogspot.com/2009/02/mechanism-of-furfural-inhibition.html
It was found that the Schottky conduction mechanism is dominant in plasma polymerized furfural thin films. The predominance of Schottky mechanism was ...
linkinghub.elsevier.com/retrieve/pii/S0040609002007009
The mechanism of xylose dehydration involves the formation of transient enediol intermediates prior to cyclization into furfural (Antal et al., 1991). ...
linkinghub.elsevier.com/retrieve/pii/S092666909700037X
A Consistent Mechanism of Furfural Formation-The aldopentoses studied differ mainly in the steric positioning of the hydroxyl func- ...
doi.wiley.com/10.1002/jps.2600580703
Our results suggest that in situ detoxification of furfural and HMF is possible and a mechanism of the detoxification is due to NADH/NADPH dependent reduction of the functional group aldehyde to the alcohol.
www.ars.usda.gov/research/publications/publications.htm... www.ars.usda.gov/research/publications/publications.htm?seq_no_115=206892
The kinetics of oxidation of furfural by peroxomonosulfuric acid (PMSA) have been studied in aqueous medium in the pH range 0-4.73 at 308 K. The reactions obey second-order kinetics, first-order each with respect to [furfural] and [PMSA].
cat.inist.fr/?aModele=afficheN&cpsidt=17817913
By comparing an evolved, furfural-resistant strain and its parent in microaerobic, glucose-limited chemostats at increasing furfural challenge, we elucidate key mechanism and the molecular basis of both natural and high-level furfural resistance.
aem.asm.org/cgi/content/abstract/75/24/7631
Finally, the possible mechanism of furfural perturbation in the oscillating reaction is discussed.When the furfural was injected into the Mn(II)-catalyzed B-Z oscillating system, the change in the amplitude and/or period was linearly proportional to the logarithm of the concentration of furfural over the range 3 x 10(-8)
www.medscape.com/medline/abstract/16505986
One postulation is that this reaction involves radical mechanism. Therefore, one part of our research has been focused on mapping the energy profile, particularly locating the transition state of the bromination reaction of furfural.
acs.confex.com/acs/swrm06/techprogram/P37350.HTM
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