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Ring strain makes epoxides more reactive than simple ethers. ... Epoxide chemistry will be discussed more in Chapter 16. ... reaction of epoxide with organometallic reagents...
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reactivity of the epoxides by ring-opening can be enhanced ..... nucleophile for epoxide ring opening reactions due to its low ...
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Epoxide - Wikipedia, the free encyclopedia
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Akbar Heydari*, Morteza Mehrdad, Aziz Maleki, Nafiseh Ahmadi ... *Chemistry Department, Tarbiat Modarres University, P. O. Box 14155-4838, Tehran, Iran, Email: akbar.heydari gmx.de ... see article for more examples...
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Author Topic: Non-terminal epoxide ring opening (Lewis acid catalysts) (Read 581 times) ... There is some little information about metal salen complexes that can work for general epoxide ring opening, but most of them either make a selective opening to OH,OH or other types.
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The Medscape Journal ... Allergy & Clinical Immunology ... Diabetes & Endocrinology...
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Reaction of aniline with various glycidic ethers gave the amino alcohols by regioselective nucleophilic attack at the terminal carbon atom of the epoxide ring as the only/major product. Zinc(II) perchlorate hexahydrate was found to be the best catalyst compared to other metal perchlorates.
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