Allylic rearrangement - Wikipedia, the free encyclopedia
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An allylic rearrangement or allylic shift is an organic reaction in which the double bond in an allyl chemical compound shifts to the next carbon atom. It is encountered in nucleophilic substituti...
en.wikipedia.org/wiki/Allylic_rearrangement
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A new one-pot method is described for the removal of O- and N-allyl protecting groups under oxidative conditions at near neutral pH. The allyl group undergoes hydroxylation and subsequent periodate scission of the vicinal diol.
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www.organic-chemistry.org/abstracts/literature/764.shtm
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Hutchinson encyclopedia article about allyl group. allyl group. Information about allyl group in the Hutchinson encyclopedia. ... Derivatives with a propyl instead of an allyl group were less active or inactive.
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encyclopedia.farlex.com/allyl+group
encyclopedia.farlex.com/allyl+group
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Hutchinson encyclopedia article about allyl. allyl. Information about allyl in the Hutchinson encyclopedia. allyl group, allyl radical ... In chemistry, the propenyl group, an unsaturated organic radical corresponding to the formula CH2:CHCH2 . ... The chief compounds are allyl alcohol (propenol), with the general properties of...
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encyclopedia.farlex.com/allyl
encyclopedia.farlex.com/allyl
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A new one-pot method is described for the removal of O- and N-allyl protecting groups under oxidative conditions at near neutral pH. The allyl group undergoes hydroxylation and subsequent periodate scission of the vicinal diol, followed by repetition of this reaction sequence on the enolic form of the aldehyde intermediate.
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pubs.acs.org/doi/abs/10.1021/ol016278t
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The allyl group, which serves as a protecting group for an internucleotide bond for both phosphates and phosphorothioates, can be easily removed by good nucleophiles under weakly basic or neutral conditions. ... Department of Medicinal Chemistry, Isis Pharmaceuticals, Carlsbad, ... In papers with more than one author,
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pubs.acs.org/cgi-bin/abstract.cgi/orlef7/2000/2/i03/abs...
pubs.acs.org/cgi-bin/abstract.cgi/orlef7/2000/2/i03/abs/ol9910518.html
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An allyl group is an alkene hydrocarbon group with the formula H2C=CH-CH2-. It is made up of a vinyl group, CH2=CH-, attached to a methylene -CH2. For example allyl alcohol has the structure H2C=CH-CH2OH . Compounds containing the allyl group are often...
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www.bookrags.com/Allyl
www.bookrags.com/Allyl
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