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Chirality (mathematics) - Wikipedia, the free encyclopedia
In geometry, a figure is chiral (and said to have chirality ) if it is not identical to its mirror image, or more particularly if it cannot be mapped to its mirror image by rotations and translati...
en.wikipedia.org/wiki/Chirality_(mathematics)
In a modified version of the classical Pasteur experiment, the enantiomorphous crystals were sorted out from a 1:1 mixture by the selective adhesion of cells to the (R,R) crystals. This stereospecificity results from molecular recognition between chiral components on the cell surface and the structured crystal surface.
www.sciencemag.org/cgi/content/abstract/263/5152/1413
Similar to the induction of homochirality in achiral enantiomorphous monolayers by a chiral modifier, a small enantiomeric excess suffices to ensure that the entire molecular monolayer consists of domains having only one of two possible, non-superimposable, mirror-like lattice structures...
www.medscape.com/medline/abstract/16437111
Unbound MEDLINE | Amplification of chirality in two-dimensional enantiomorphous lattices. Journal article. Search by keyword, journal, author or by EBM filters diagnosis, treatment, prognosis or etiology. Evidence-based medicine search filters. ... Amplification of chirality in two-dimensional enantiomorphous lattices.
www.unboundmedicine.com/medline/ebm/record/16437111/abs... www.unboundmedicine.com/medline/ebm/record/16437111/abstract/Amplification_of_chirality_in_two_dimensional_enantiomorphous_lattices
We report the induction of homochirality in enantiomorphous layers of achiral succinic acid on a Cu(110) surface after doping with tartaric acid (TA) enantiomers. Succinic acid becomes chiral upon adsorption due to symmetry-breaking interactions with the Cu(110) surface. ... After thermally induced desorption of TA, ... J. Am. Chem.
pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2004/126/i47/a... pubs.acs.org/cgi-bin/abstract.cgi/jacsat/2004/126/i47/abs/ja044136z.html
Monoclonal antibodies were selected after immunization with crystals of the tripeptide l-leucine-l-leucine-l-tyrosine. They interact with the tripeptide crystals, but do not interact with the tripeptide molecule, with other crystalline surfaces, or with adsorbed protein. ... Publication Date (Web): December 24, 2002...
pubs.acs.org/doi/abs/10.1021/ja027942j
From the following article: ... Roman Fasel, Manfred Parschau & Karl-Heinz Ernst ... Nature 439, 449-452(26 January 2006)
www.npg.nature.com/nature/journal/v439/n7075/suppinfo/n... www.npg.nature.com/nature/journal/v439/n7075/suppinfo/nature04419.html
From the following article: ... Roman Fasel, Manfred Parschau & Karl-Heinz Ernst ... Enantiomorphous domains of racemic heptahelicene on Cu(111).
www.nature.com/nature/journal/v439/n7075/fig_tab/nature... www.nature.com/nature/journal/v439/n7075/fig_tab/nature04419_ft.html
Most of the articles and textbooks that show drawings of enantiomorphous crystals use an inadequate view to appreciate the fact that they are non-superimposable mirror images of one another.
jchemed.chem.wisc.edu/journal/issues/2007/Nov/abs1783.h... jchemed.chem.wisc.edu/journal/issues/2007/Nov/abs1783.html